Climatic and environmental profile of Ukrainian regions and their impact on architectural metals
To conduct an objective and deep comparative analysis, it is necessary to classify the selected regions of Ukraine in accordance with generally accepted international norms, in particular the standards of the environmental corrosivity assessment series. According to this classification, the environment is divided into several categories: from the first (very low activity, inherent in heated premises with a neutral atmosphere) to the fifth (very high activity, covering industrial zones with high humidity and coastal areas with intensive salinization) and the extreme category, which is applied for the most severe operating conditions, such as marine oil platforms.
Each of the studied regions of Ukraine forms a unique set of challenges for the durability of metal coatings, which requires a specific engineering approach to the design of facade and fencing systems.
Mountain climate of the Carpathians (Corrosivity category from second to third)
The Carpathian macroregion is distinguished by a moderate continental climate, characterized by an extremely high level of atmospheric precipitation, significant daily temperature fluctuations, and a high probability of dense fogs forming in the morning and evening hours. The high level of natural humidity creates conditions for a significant prolongation of the time of wetness on the surfaces of building structures. However, from the point of view of the chemical composition of the atmosphere, this region remains the cleanest among all considered locations.
The absence of large-scale industrial complexes, metallurgical plants, relatively low density of traffic flows, and the complete absence of marine salts in the air determine the neutral character of the moisture settling on the metal. Atmospheric pollution by sulfur dioxide or other aggressive gases in the mountains is minimal, often approaching zero values. Consequently, classic electrochemical corrosion develops extremely slowly here.
The main threat to the durability of metal structures covered with polymer paints in a high-altitude environment is not the dissolution of the zinc layer, but the photochemical degradation of the finish coating under the influence of intense solar radiation. At high altitudes above sea level, ultraviolet radiation is much harsher, which inevitably leads to accelerated destruction of polymer bonds in cheap paints, causing them to fade, change their original shade, lose gloss, and gradually micro-crack. Therefore, for projects in the Carpathians, the key selection criterion is not the maximum thickness of zinc protection, but the presence of a premium polymer coating resistant to prolonged solar exposure, while the requirements for the base anti-corrosion layer can remain within standard values for clean environments.
Industrial climate of Kryvyi Rih (Corrosivity category four)
Kryvyi Rih represents a unique example of an urbanized territory with an extreme level of technogenic load on the environment, forming extremely hostile conditions for any building materials. According to official environmental monitoring data, over eighty-seven percent of all industrial air emissions in the city are generated by a single metallurgical giant, whose activities are supplemented by several powerful mining and processing plants. Elevated concentrations of a number of aggressive chemical compounds are stably recorded in the city’s air basin, including sulfur dioxide, carbon monoxide, nitrogen oxides, phenol, ammonia, and huge volumes of heavy industrial dust.
The mechanism of accelerated destruction of metals in such an environment is triggered when atmospheric moisture (during rain or dense fog) reacts chemically with sulfur dioxide. As a result of this interaction, sulfurous acid is formed, which falls on the surface of facades and fences in the form of acid rain. Such an acidic environment is catastrophic for a standard zinc coating: the acid instantly reacts with zinc, forming water-soluble salts that are simply washed away by the next rain. This continuous process leads to a rapid thinning of the protective layer, leaving the base steel defenseless against rust. The rate of corrosion degradation of metal in such conditions grows exponentially.
An additional and extremely powerful degradation factor is specific mineral dust. Residents and ecologists of Kryvyi Rih periodically record the formation of atypical dense coatings on the surfaces of external objects. Spectral analyses confirm that this dust contains a significant proportion of magnetite particles, which are a direct consequence of mining production. This heavy dust quickly settles on the horizontal planes of fences, windowsills, and decorative facade elements. The dust not only soils the appearance, it acts like a sponge: it accumulates atmospheric moisture and the acidic gases dissolved in it, creating an ideal, constantly active compress for continuous electrochemical destruction of the protective polymer coating under a layer of dirt.
Marine climate of Odesa (Corrosivity category from fourth to fifth)
Odesa represents perhaps the harshest test for metal architectural systems in Ukraine. The city’s climatic picture combines constant high humidity (whose average annual indicator stays at the level of seventy-five percent), the specific aerodynamics of sea winds, and a significant number of sunny hours per year. In winter, due to the combination of high humidity with piercing wind currents, temperature comfort drops sharply. The city periodically faces a dangerous meteorological phenomenon — “glaze ice from the sea,” when a moisture-saturated Atlantic air current collides with continental cold and instantly covers all external building structures with a thick layer of ice.
However, the main and most dangerous catalyst for metal destruction here is sea salt, consisting mainly of chlorides. Microscopic salt particles are constantly carried by wind masses from the sea area and settle densely on the surfaces of metal fences, facade cassettes, and fasteners. The unique danger of chlorides lies in their hygroscopicity — the ability to actively attract water molecules from the surrounding air even in the absence of direct rain or fog. This leads to the formation of a highly conductive solution of salt dew on the metal surface, which sharply increases the overall time of wetness of the structure.
Moreover, chlorides have the ability to chemically destroy the passive oxide film on the surface of zinc and stainless steel. Instead of forming a stable protective barrier (for example, insoluble zinc carbonate, as happens in clean air), zinc in a marine environment turns into zinc chloride and zinc hydroxide — soluble jelly-like compounds that are quickly washed away by precipitation, exposing fresh layers of metal to further attack. This causes dangerous pitting (or localized) corrosion, which penetrates extremely quickly deep into the material, creating deep craters in the steel.
According to the international classification of corrosivity, the immediate coastal strip of Odesa (at a distance of up to five hundred meters from the water’s edge) unequivocally belongs to the fifth, very high category of aggressiveness. Areas of the city located deeper inland correspond to the fourth category. The use of ordinary galvanized steel with a basic paint layer in such extreme conditions is a gross engineering mistake, since the structure can completely lose its functions and become covered with through-rust in just a few years of operation.